HomeAutoNew proton conductor for next-generation proton ceramic gasoline cells: Ba2LuAlO5 Get hold...

New proton conductor for next-generation proton ceramic gasoline cells: Ba2LuAlO5 Get hold of US

A workforce of researchers led by Tokyo Tech reports that the oxide Ba2LuAlO5 is a promising proton conductor for protonic ceramic gasoline cells. Experiments present that this novel materials has a remarkably excessive proton conductivity even with none extra chemical modifications, and molecular dynamics simulations reveal the underlying causes. An open-access paper on the work is revealed in Communications Supplies.

Proton conductors have discovered numerous purposes, corresponding to electrolytes in proton ceramic gasoline cells, which require excessive ionic conductivity at low temperatures and excessive chemical stability. Right here, we report the oxide, Ba2LuAlO5, which reveals proton conductivities of 10−2 S cm−1 at 487 °C and 1.5 × 10−3 S cm−1 at 232 °C, excessive diffusivity and excessive chemical stability with out chemical doping.

Ba2LuAlO5 is a hexagonal perovskite-related oxide with extremely oxygen-deficient hexagonal close-packed h′ layers, which allows a considerable amount of water uptake x = 0.50 in Ba2LuAlO5·x H2O. Ab initio molecular dynamics simulations and neutron diffraction present the hydration within the h′ layer and proton migration primarily round cubic close-packed c layers current on the interface of octahedral LuO6 layers. These outcomes show that the excessive proton conduction allowed by the extremely oxygen-deficient and cubic close-packed layers is a promising technique for the event of high-performance proton conductors.

—Morikawa et al.

Typical strong oxide gasoline cells have a notable disadvantage in that they function at excessive temperatures, often above 700 °C. Many scientists consequently have centered on protonic ceramic gasoline cells (PCFCs) as an alternative. These cells use particular ceramics that conduct protons (H+) as an alternative of oxide anions (O2−). As a result of a a lot decrease working temperature within the vary of 300 to 600 °C, PCFCs can guarantee a steady vitality provide at a decrease price, in comparison with most different gasoline cells. Sadly, only some proton-conducting supplies with affordable efficiency are at present identified, which is slowing down progress on this area.

Professor Masatomo Yashima from Tokyo Institute of Expertise (Tokyo Tech) and colleagues found Ba2LuAlO5 whereas specializing in discovering compounds with a number of intrinsic oxygen vacancies. This was motivated by the outcomes of earlier research highlighting the significance of those vacancies in proton conduction.

Experiments on Ba2LuAlO5 samples revealed that this materials has a excessive proton conductivity in its bulk at low temperatures even with out extra chemical refinements corresponding to doping.

Afterwards, the workforce sought to seek out out the underlying causes for this property. By means of molecular dynamics simulations and neutron diffraction measurements, they discovered two necessary traits of Ba2LuAlO5. The primary is that this oxide absorbs a number of water (H2O), in comparison with different related supplies. This massive water uptake, which happens inside two opposing layers of AlO4 tetrahedra, is made doable by a excessive variety of intrinsic oxygen vacancies within the hexagonal close-packed h´ BaO layers. In flip, the oxide’s increased water content material will increase its proton conductivity via numerous mechanisms, corresponding to increased proton focus and enhanced proton hopping.

The second necessary attribute is said to how protons transfer via Ba2LuAlO5. Simulations revealed that protons diffuse primarily alongside the interfaces of LuO6 layers, which kind cubic close-packed c BaO3 layers, fairly than via the AlO4 layers. This data could possibly be crucial within the seek for different proton conducting supplies.

The researchers anticipate finding different proton-conducting supplies based mostly on Ba2LuAlO5 in upcoming research.

By modifying the chemical composition of Ba2LuAlO5 , additional enhancements in proton conductivity could be anticipated. For instance, the perovskite-related oxide Ba2InAlO5 may exhibit excessive conductivity since its construction is kind of much like that of Ba2LuAlO5.

—Prof Yashima


  • Morikawa, R., Murakami, T., Fujii, Ok. et al. (2023) “Excessive proton conduction in Ba2LuAlO5 with extremely oxygen-deficient layers.” Commun Mater 4, 42 doi: 10.1038/s43246-023-00364-5

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